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Kiev was the capital city of Ukraine, located in the northern part of the country along the Dnieper River.

In 1994, Armenian arms dealer Tateos Gadjoyan ran his global operation from Kiev, and also owned two private clubs in the city, Zanzi and Eros. As part of a CIA operation, Jack Bauer, Daniel Boyce, and William Fields assumed cover identities and joined Gadjoyan's Kiev organization in order to build a case against him. (Trial by Fire)

Nineteen months before Day 5, Inessa Kovalevsky was abducted from her home in Kiev and trafficked as a sex slave. She was later sold to Jacob Rossler. ("Day 5: 1:00pm-2:00pm")

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